The only technology in the world that makes conventional plastics biodegradable in landfills, anaerobic digesters, compost facilities, and the ocean.
Breaking News: Earth Nurture, KhaiEL Korea, and KhaiEL Gmbh have formed a new company to exploit Earth Nurture technology in the bioremediation of many industrial effluents and toxic spills, as well as making and distributing ENA masterbatch for making conventional plastics biodegradable. The new company, ENA Biotec, is incorporated in South Korea. Our projects include bioremediating secondary and tertiary amine containing wastewater from gas sweetening plants and fertilizer factories, dye wastwater bioremediation, and bioremediating many other toxins including petroleum products, BTEX compounds, polycyclic aromatic hydrocarbons, and wastes from the manufacture and distribution of herbicides and pesticides.
Due to a recent ruling by an administrative judge, (in February 2015,) ENA-treated plastics, such as LDPE, can now be labeled as 'biodegradable' in the United States, without any qualification. The state of California does not permit this designation, but federal regulations permit it when there has been a positive ASTM D5511 test for biodegradation. ENA has tested positive for biodegradation in an ASTM D5511 test.
At Earth Nurture, we are dedicated to seeing that more and more of the plastic disposable items we use every day rejoin the cycle of life. We sell Earth Nurture masterbatch additive for rendering conventional plastics biodegradable in commercial compost facilities, landfills, anaerobic digesters, and in natural bodies of water.
Earth Nurture has a masterbatch additive for every common plastic, and many uncommon ones. Earth Nurture has a masterbatch additive that will cause the biodegradation in commercial composters, natural bodies of water, and landfills of: Polypropylene (PP,) Polyethylene (PE,) Low Density Polyethylene (LDPE,) High Density Polyethylene (HDPE,) PET ( Polyethylene terephthalate ,) Polystyrene (PS,) Expanded Polystyrene (EPS, sometimes called Styrofoam, which is a trademarked brand of EPS,) Nylon, and even Polylactic Acid (PLA.)
(A masterbatch additive is an additive which is added to the masterbatch, which is the plastic as it is being melted for final fabrication into sheets or molded products.)
Biodegradable Plastic Technologies Available - A comparison
Table Demonstrating Aerobic Biodegradation of ENA-Treated LDPE Sample
The History of Biodegradable Plastics
Because there are a number of different approaches to biodegrading plastic, and because people have developed so many misconceptions about biodegradable plastics, I have written a brief history of biodegradable plastics. There have been three generations of biodegradable plastic. The first was starch based plastic, PLA, almost always made out of corn. The second generation was oxo-biodegradable conventional plastic, and the third, the current generation, is microbiodegradable conventional plastic.
PLA, or corn-based biodegradable plastic
PLA, or corn-based biodegradable plastic, was said to be the first generation of biodegradable plastic, even though its primary manufacturer, Naturworks, states that it will not biodegrade in any natural environment, nor in landfills. PLA, Poly Lactic Acid, biodegrades only in commercial compost facilities - and many commercial compost facilities refuse to accept PLA. It is made and promoted by corporate giants that have huge financial and political power, such as Cargill, Inc., but it has many drawbacks.
It is billed as ***'sustainable,' as it is based on food sources, primarily corn. However, if all of the disposable plastic products in the world were made out of corn, 238,500,000 tons of corn would be used to make plastic. Prices for corn would rise dramatically, and third world hunger would increase even more dramatically. There are currently 1,000,000,000 hungry people in the third world, says the UN. If the amount of plastic disposables, such as packaging and drinking cups from fast food stands used in the US each year were all made of corn, it would take 18% of the country's farm land to fill the need. That is enough food to feed over 600 million people, people who need that food desperately. If we imagine their condition worsening only slightly, the result could only be a humanitarian catastrophe of appalling proportions. That is the real ramification of 'sustainability' in today's world.
Furthermore, PLA isn't a very good plastic. It imparts an off taste to water when used for water bottles, it melts when used as soup spoons, it's weak, and therefore items made of it are heavy, and it has a short shelf life, sometimes becoming a sticky mess while still in the warehouse. What's more, no recyclers accept it for recycling except the company that manufactures it, which ships it across the US to its one recycling center. In fact, recyclers that don't manufacture PLA, dislike PLA and are trying to ban it, because it gets confused with more conventional plastics, and ruins their recycled plastic batches.
Even the few commercial composters which accept PLA products have a limited appetite for PLA, because it adversely affects the compost batch as too much PLA makes the compost too acidic. One bottle manufacturer did a survey of commercial composters and found that 90% of those surveyed would not accept PLA bottles. Furthermore, PLA cannot be composted by home composters - PLA requires elevated heat beyond what home compost processes generates to compost. The most peculiar thing about calling PLA compostable, is that it leaves no residue in compost, and so it gives no contribution to humus. The ASTM standard for compostable plastic, ASTM D6400, actually requires that compostable plastic makes no contribution to humus. (For information about the effect of the corn boom on the environment, click here.)
Oxo - Biodegradable Plastic, the Second Generation of Biodegradable Plastic
The second generation plastic oxo - biodegradable plastic was very different than the the previous generation of biodegradable plastic called PLA, starch-based plastic, or 'spudware. Oxo-biodegradable plastic had many advantages over PLA-It was invulnerable to water, one might adjust it to the desired biodegradation rate, some products could contain recycled content, it could be recycled, it didn't diminish the grain supply, it was stronger, less expensive, and was made from an otherwise useless industrial byproduct, light naphtha. (Light naphtha is a highly volatile faction of crude oil that cannot be made into gasoline, diesel, fuel oil, or jet fuel.**)
This second-generation biodegradable plastic is little known in the US, but is is well established and widely used in Europe. Tesco and Carrefours, the largest grocery chains in the world, and in France, respectively, package their customers' groceries in oxo-biodegradable 't-shirt' bags. In fact, the largest bakers in Mexico and South Africa package bread in oxo - biodegradable bags, and oxo - biodegradable plastic is becoming common in India and China. The US is so far behind the curve on this, that it is a little embarrassing. (Update: Tesco has stopped using biodegradable plastic shopping bags, citing a study by DEFRA which reflected all of the issues I have cited.) Read the DEFRA report by clicking here.
Oxo - biodegradable plastic doesn't biodegrade when deeply buried in landfills*, because it requires an initial phase of degeneration which required certain environmental factors-oxygen and one of the following three circumstances-heat, UV light, or mechanical stress-and because the subsequent biodegredation part of the degredation only works in oxygenated environments. These circumstances don't exist when deeply buried in landfills, so oxo-biodegradable plastics don't have any benefit for products deeply buried in landfills. Oxo - biodegradable products may, however, offer a benefit if litter is the primary concern, as they degrade in the presence of UV light.
There is a potential problem with UV initiated degradation, however - if it becomes common and products made with oxo-biodegradable additives enter the recycling stream in large numbers, the resulting plastic could have a short lifespan if placed in sunlight. This would be a big problem for items made with recycled plastic such as plastic tarps.
The Third Generation of Biodegradable Conventional Plastics,
which are used in our products: Micro - biodegradable Plastic
There is now a third generation biodegradable plastic product which is the standard plastic we use daily, light naphtha based plastic, with a masterbatch additive (ENA or Earth Nurture Additive,) that will cause it to biodegrade without the need of heat, UV light, mechanical stress, or oxygen. This third-generation plastic is called micro - biodegradable plastic, and it biodegrades when placed into the ground due to the action of micro-organisms naturally occurring in soil.
We now have ENA 2.0 masterbatch additive formulas for biodegrading all common plastics - Polypropylene, Polyethylene, HDPE, LDPE, LLDPE, Polystyrene, Expanded Polystyrene, Nylon, and many others, including PLA. Products made with our ENA 2.0 additives are recyclable, invulnerable to water, don't diminish the grain supply, and are much less expensive than bioplastics. Products made with our additives also have the advantage of having the same shelf life as regular plastics, unlike PLA and oxo - biodegradable plastic, as it does not biodegrade until it is in the presence of soil micro-organisms.
Additionally, this new ENA micro - biodegradable plastic will definitely biodegrade when buried in the ground in either aerobic or anaerobic environments, that is, landfills and anaerobic digesters. If ENA-treated plastic is biodegraded in airless or very low oxygen environments, such as landfills or anaerobic digesters, it produces valuable methane gas. Over 60% of landfilled solid waste in the United States is disposed of in landfills that are tapped for methane, and the resulting methane, which is essentially the same as natural gas, can be used for many purposes. It is being piped into homes for cooking and heating, it is piped to factories for industrial production, it is used to run turbines to make electricity, and it is used to operate vehicles such as buses, taxis, and private automobiles. Few Americans know that millions of vehicles are being run on natural gas / methane. The latest in natural gas storage, adsorbed natural gas tanks, makes the use of methane in vehicles safe, inexpensive, and convenient.
Why does the world need for plastic to be biodegradable?
- "Xiao Flin, a farmer in Manas County, spent a lot of time getting rid of the residual mulch in his 40-mu field, but his efforts were in vain.
Scooping up a handful of soil, Xiao found four or five pieces of mulch film in his hand, with the longest measuring 30 cm. Heavy residues have blocked the water from penetrating into the soil, which is detrimental.
According to research by the Xinjiang Academy of Agricultural Sciences (XAAS), when the residues reach 52.5 kg per hectare, cotton production decreases by 15 percent....
Farmer Sun Wenchuan from Yuli County said that it is not easy to collect the residue of thicker mulch films either. It's expensive and time-consuming and has to pay 3,000 yuan for manual collection of residue in his fields.
Li Zhong, head of Yuli County's agricultural bureau, admitted battling residual mulch has been difficult due to lack of effective recycling tools. Less than half of the mulch film could be collected from the soil by machine."
"Environmental impacts are wide ranging and can be both direct and indirect. Direct impacts occur when marine life is physically harmed by marine debris through ingestion or entanglement (e.g., a turtle mistakes a plastic bag for food) or marine debris physically alters a sensitive ecosystem (e.g., a fishing net is dragged along the ocean floor by strong ocean currents and breaks and smothers a coral reef). Environmental impacts can also be indirect, such as when a marine debris cleanup results in ecological changes."
Please e-mail Tim Dunn for any inquiries, including documentation of any claim made on this website. We have extensive documentation of third party testing of the biodegradability, acceptability for food contact, and environmental harmlessness of our products.
February, 2015 - Newsflash! There has been a trial in the United States concerning the advertising and labeling of biodegradable plastics. The trial was by an administrative law judge with jurisdiction over the US Federal Trade Commission (FTC), and the parties were the FTC versus ECM Biofilms Inc., Docket Number 9358. The "Initial Decision" was dated January 28, 2015.
The findings that I have gleaned from this 330 page document are that: 1) The judge threw out the FTC's claim that "biodegradable" means that a substance will biodegrade in one year; 2) The judge determined that ASTM D5511 is a valid test for determining the biodegradability of a substance, including biodegradability in a landfill; 3) That no existing test can determine the rate of the biodegradation of any substance in a landfill, so no claims of a time frame for biodegradation of any product in a landfill may be made.
The net result of the above is that it is legal to call a product biodegradable in the US if any amount of biodegradation, that exceeds the percentage of the prodegradant additive's own biodegradation, has been demonstrated with the anaerobic biodegradation test, ASTM D5511, but that no claims for the rate of biodegradation in a landfill may be made. Note, however, that the state of California prohibits calling any product biodegradable. The state of California does permit a product to be called compostable if it meets ASTM D6400, a test for compostability of plastics in a specific aerobic environment. The state of California holds about 12% of the population of the United States.
A press release concerning this may be found at: FTC Press Release
October, 2014 - Earth Nurture has obtained funding for full EN 13432 / ASTM D6400 testing, and has arranged a manufacturing chain for ENA, with a company that was spun off from the German chemical giant, Bayer.
June, 2014 - Earth Nurture has produced a film made with 30% renewable content. Full sized manufacturing of ENA-treated polyethylene film has been demonstrated on a commercial plastic film line, and the film was demonstrated to be completely weldable. The film underwent no visible changes after being stored in a warm, dry environment for six months, and could not be distinguished from untreated film.
Tim is a frequent contributor to the Linkedin group, Biodegradable Plastics.
PET, the clear plastic used in soda and water bottles, is being made partly out of materials of plant origin by the largest bottlers, and Nestle has decided that PLA (corn plastic, or polylactic acid,) is not practical for widespread packaging use. So, in response to the public demand for 'sustainability,' industry is starting to supply "conventional" plastics with at least partly plant-based materials.
The Brazilian Braskem corporation is building a production plant with an annual capacity of 200,000 tons for the production of bio-PE. The current production figures presently run to only 12 t per year in a pilot plant . The two companies Dow and Crystalsev have also announced that they will build a plant for the production of bio-PE with an annual production capacity of 350,000 tons. Source: http://www.bio-plastics.org/joomdocs/BioplasticsMarket.pdf [Bio-PE is made from plant sources, but it is not biodegradable, unless you add ENA to it.]
"We all have read about the recent announcements, by H.J. Heinz Co. to use Coca-Cola's TM 30% plant-based PET PlantBottle for packaging its ketchup, and then by PepsiCo TM announcing the existence of a 100% plant-based PET bottle in the laboratory and shortly thereafter Coca-Cola TM itself announcing the 100% PlantBottle for Dasani TM." [Like bio-PE, bio-PET is made from plant sources, but it is not biodegradable, unless you add ENA to it.]
A very large and highly technical study about the environmental benefits of conventional plastic garbage bags versus bioplastic garbage bags (PLA, aka corn-plastic,) bags has just been released. Conventional plastic was found to be more environmentally friendly in all categories, including non-renewable energy use, global warming impact, and pollution.
Bagasse (sugar cane) residue is a compostable product made out of an agricultural byproduct. So far, so good. Is it suitable for making plates, lunch trays, bowls, and other food service ware out of? This chef puts it to the test.
Is bottled water the pointless expense many 'Greens' say it is? No, chlorinated tap water causes cancer. Thousands of cases of cancer every year. Click here to read a definitive study.
**It is often implied, quite mistakenly, that a barrel of oil could easily be turned into whatever product is desired. Nothing could be further from the truth. A barrel of crude oil has many complex chemicals in it, of various different weights / densities. These various densities are suitable for producing only a limited number of items. 'Light' naphtha, the kind used to make plastics, is lighter than gasoline, and more dense than natural gas. It has very few uses besides making plastics. It is also used for making products in relatively limited demand, such as 'white gasoline' aka 'Coleman fuel,' lighter fluid, and solvent. Click here to see this illustrated.
***How 'sustainable' is corn? Every phase of cultivation: Planting, fertilization, weed killing, pest killing, harvesting, and transporting of harvested corn, uses diesel to run the machinery which does this work, and the fertilizer used in growing corn is also made out of petroleum. Furthermore, the process uses vast amounts of water, and pollutes the remaining ground water with pesticides and herbicides, rendering it toxic. Click here to read a Time Magazine article which expresses extreme skepticism about the greenness of biofuel.
How green are bioplastics compared to plastics made from petroleum products? Click here to see a recent study from the University of Pittsburgh
There are 280 million (American) tons of plastic (255 million metric tonnes) made every year. Worldwide production of PLA, or corn plastic, is about 500,000 tons, or about 2 tenths of one percent of the 'conventional' plastic made every year. It takes about 2.61 tonnes of corn to make one tonne of PLA, so it would take 665 million tonnes of grain to replace all of the conventional plastic with PLA. The UN says that well over a billion people are hungry right now, with a world grain production of 1.73 billion tonnes of grain. It would take 38% of the world's grain supply to make all of the world's plastic out of grain.
The thing to take away from all of this is that you can't just believe cliches or commercial claims about greenness. The gold rush to greenness has been noticed by giant commercial interests, and the public concern about our environment is being ruthlessly exploited by huge companies who have no real concern for the environment. To know what is best for the environment requires vigorous exploration of the fundamental facts, and some extensive math. There is no valid shortcut to knowing what is 'green,' but science.